The numerical solution of the Advection-Dispersion Equation: A review of some basic principles     

Steve Wallis 《Acta Geophysica》2007,55(1):85-94

The simulation of solute transport in rivers is frequently based on numerical models of the Advection-Dispersion Equation. The construction of reliable computational schemes, however, is not necessarily easy. The paper reviews some of the most important issues in this regard, taking the finite volume method as the basis of the simulation, and compares the performance of several types of scheme for a simple case of the transport of a patch of solute along a uniform river. The results illustrate some typical (and well known) deficiencies of explicit schemes and compare the contrasting performance of implicit and semi-Lagrangian versions of the same schemes. It is concluded that the latter have several benefits over the other types of scheme.  相似文献   

Evolution of the variability of surface temperature and vegetation density in the great plains     

Michael H. Cosh  Jery R. Stedinger  Steve C. Ou  Kuo-Nan Liou  Wilfried Brutsaert 《Advances in water resources》2007

This study focuses on how the variability of land surface temperature and vegetation density at the SGP ARM-CART site changes over episodic (day to day) and seasonal time scales using AVHRR satellite data. Four drying periods throughout the year are analyzed. Land surface temperature had an erratic relationship with time exhibiting no deterministic pattern from day-to-day or season-to-season. Furthermore, it did not exhibit spatial pattern persistence. On the other hand, vegetation density had a consistent spatial pattern and temporal decay during average length drying periods (less than 7 days) as well as within a season. However, there were distinct differences in the seasonal pattern of variation between winter and growing seasons. In addition, the paper highlights a methodology to quantify the relationships that exist at the land surface between the primary parameter of interest and the controlling variables.  相似文献   

Use of high spectral resolution remote sensing to determine leaf palatability of eucalypt trees for folivorous marsupials     

Steve Dury  Brian Turner  Bill Foley  Ian Wallis 《International Journal of Applied Earth Observation and Geoinformation》2001,3(4):328

In this study we assess the feasibility of remotely measuring canopy biochemistry, and thus the potential for conducting large-scale mapping of habitat quality. A number of studies have found nutrient composition of eucalypt foliage to be a major determinant of the distribution of folivorous marsupials. More recently it has been demonstrated that a specific group of secondary plant chemicals, the diformylphloroglucinols (DFPs), are the most important feeding deterrents, and are thus vital determinants of habitat quality. We report on the use of laboratory spectroscopy to attempt to identify one such DFP, sideroxylonal-A, in the foliage of Eucalyptus melliodora, one of the few eucalypt species browsed by folivorous marsupials. Reflectance spectra were obtained for freeze-dried, ground leaves using near infrared spectroscopy (NIRS) and for both oven-dried and fresh whole leaves using a laboratory-based (FieldSpec) spectroradiometer. Modified partial least squares (MPLS) regression was used to develop calibration equations for sideroxylonal-A concentration based on the reflectance spectra transformed as both the first and second difference of absorbance (Log 1/R). The predictive ability of the calibration equations was assessed using the standard error of calibration statistic (SECV). Coefficients of determination (r²) were highest for the ground leaf spectra (0.98), followed by the fresh leaf and dry leaf spectra (0.94 and 0.87, respectively). When applied to independent validation sub-sets, sideroxylonal-A was most accurately predicted from the ground leaf spectra (r² = 0.94), followed by the dry leaf and fresh leaf spectra (0.72 and 0.53, respectively). Two spectral regions, centred on 674 nm and 1394 nm, were found to be highly correlated with sideroxylonal-A concentration for each of the three spectral data sets studied. Results from this study suggest that calibration equations derived from modified partial least squares regression may be used to predict sideroxylonal-A concentration, and hence leaf palatability, of Eucalyptus melliodora trees, thereby indicating that the remote estimation of habitat quality of eucalypt forests for marsupial folivores is feasible.  相似文献   

Petroleum Hydrocarbon Bioventing Kinetics Determined in Soil Core, Microcosm, and Tubing Cluster Studies   总被引：2，自引：0，他引：2  

Ellen E. Moyer  David W. Ostendorf  Robin J. Richards  Steve Goodwin 《Ground Water Monitoring & Remediation》1996,16(1):141-153

Aerobic biodegradation of vapor-phase petroleum hydrocarbons was evaluated in an intact soil core from the site of an aviation gasoline release. An unsaturated zone soil core was subjected to a flow of nitrogen gas, oxygen, water vapor, and vapor-phase hydrocarbons in a configuration analogous to a biofilter or an in situ bioventing or sparging situation. The vertical profiles of vapor-phase hydrocarbon concentration in the soil core were determined by gas chromatography of vapor samples. Biodegradation reduced low influent hydrocarbon concentrations by 45 to 92 percent over a 0.6-m interval of an intact soil core. The estimated total hydrocarbon concentration was reduced by 75 percent from 26 to 7 parts per million. Steady-state concentrations were input to a simple analytical model balancing advection and first-order biodegradation of hydrocarbons. First-order rate constants for the major hydrocarbon compounds were used to calibrate the model to the concentration profiles. Rate constants for the seven individual hydrocarbon compounds varied by a factor of 4. Compounds with lower molecular weights, fewer methyl groups, and no quaternary carbons tended to have higher rate constants. The first-order rate constants were consistent with kinetic parameters determined from both microcosm and tubing cluster studies at the field site.  相似文献   

Elucidation of the Alum Shale kerogen structure using a multi-disciplinary approach     

Sunil Bharati  Richard L. Patience  Steve R. Larter  Guy Standen  Iain J. F. Poplett 《Organic Geochemistry》1995,23(11-12)

The significance and validity of integrating data obtained from a variety of analytical techniques to understand, elucidate and model kerogen's complex chemical structure is reported here using degradative (open and closed system pyrolysis, chemical oxidation), non-degradative (¹³C CP/MAS NMR) and optical (incident white light and blue light) methods. Seven Cambrian Alum Shale samples, ranging in maturity from immature to post-mature with respect to petroleum generation, were studied and were chosen for their simple geological history, uniform organic matter type and high organic carbon content. The Alum Shale kerogens, which primarily consist of algal organic matter, liberate low molecular weight gaseous and aromatic compounds on pyrolysis and give mostly branched dicarboxylic acids on chemical oxidation. ¹³C NMR spectroscopy shows that the Alum Shale kerogens are anomalously rich in oxygen-bearing functional groups (such as C = O, ArCO, CHO, CH_xO), most of which apparently remain intact within the kerogen macro-molecule (KMM) through the diagenetic and catagenetic stages. Fragments released by different degradative techniques are quantified and the aromaticity (f_a), O/C and relative proportions of various carbon types estimated by ¹³C NMR. A synthesis of these data has allowed us to better understand the chemistry of the Alum Shale kerogen.  相似文献   

An overview of toxicant identification in sediments and dredged materials   总被引：1，自引：0，他引：1  

Ho KT  Burgess RM  Pelletier MC  Serbst JR  Ryba SA  Cantwell MG  Kuhn A  Raczelowski P 《Marine pollution bulletin》2002,44(4):286-293

The identification of toxicants affecting aquatic benthic systems is critical to sound assessment and management of our nation's waterways. Identification of toxicants can be useful in designing effective sediment remediation plans and reasonable options for sediment disposal. Knowledge of which contaminants affect benthic systems allows managers to link pollution to specific dischargers and prevent further release of toxicant(s). In addition, identification of major causes of toxicity in sediments may guide programs such as those developing environmental sediment guidelines and registering pesticides, while knowledge of the causes of toxicity which drive ecological changes such as shifts in benthic community structure would be useful in performing ecological risk assessments. To this end, the US Environmental Protection Agency has developed tools (toxicity identification and evaluation (TIE) methods) that allow investigators to characterize and identify chemicals causing acute toxicity in sediments and dredged materials. To date, most sediment TIEs have been performed on interstitial waters. Preliminary evidence from the use of interstitial water TIEs reveals certain patterns in causes of sediment toxicity. First, among all sediments tested, there is no one predominant cause of toxicity; metals, organics, and ammonia play approximately equal roles in causing toxicity. Second, within a single sediment there are multiple causes of toxicity detected; not just one chemical class is active. Third, the role of ammonia is very prominent in these interstitial waters. Finally, if sediments are divided into marine or freshwater, TIEs perforMed on interstitial waters from freshwater sediments indicate a variety of toxicants in fairly equal proportions, while TIEs performed on interstitial waters from marine sediments have identified only ammonia and organics as toxicants, with metals playing a minor role. Preliminary evidence from whole sediment TIEs indicates that organic compounds play a major role in the toxicity of marine sediments, with almost no evidence for either metal or ammonia toxicity. However, interpretation of these results may be skewed because only a small number of interstitial water (n = 13) and whole sediment (n = 5) TIEs have been completed. These trends may change as more data are collected.  相似文献   

The clustering of K∼20 galaxies in 17 radio galaxy fields     

Nathan Roche  Steve Eales  & Hans Hippelein 《Monthly notices of the Royal Astronomical Society》1998,295(4):946-958

We investigate the angular correlation function, ο(θ), of the galaxies detected in the 2.1-μm K ' band in 17 fields (101.5 arcmin² in total), each containing a z ∼1.1 radio galaxy. There is a significant detection of galaxy clustering at a limit of K ∼20, with a ο(θ) amplitude similar to that estimated by Carlberg et al. at K =21.5. The ο(θ) amplitudes of these K -limited samples are higher than expected from the faint galaxy clustering in the blue and red passbands, but consistent with a pure luminosity evolution model if clustering is stable (ε=0) and the correlation function of early-type galaxies is steeper than that of spirals.
We do not detect a significant cross-correlation between the radio galaxies and the other galaxies in these fields. The upper limits on the cross-correlation are consistent with a mean clustering environment of Abell class 0 for z ∼1.1 radio galaxies, similar to that observed for radio galaxies at z ∼0.5, but would argue against an Abell class 1 or richer environment. As Abell 0 clustering around the radio galaxies would not significantly increase the ο(θ) amplitude of galaxies in these fields, stable clustering with a steep ξ( r ) for E/S0 galaxies appears to remain the most likely interpretation of the ο(θ) amplitude.
At K ≤20, the number of galaxy–galaxy pairs of 2–3 arcsec separation exceeds the random expectation by a factor of 2.15±0.26. The excess of close pairs is comparable to that previously reported for R -band data, and consistent with a ∼(1+ z )² evolution of the galaxy merger rate.  相似文献   

Modelling the redshift-space distortion of galaxy clustering     

Steve Hatton  & Shaun Cole 《Monthly notices of the Royal Astronomical Society》1998,296(1):10-20

  相似文献   

Mock 2dF and SDSS galaxy redshift surveys   总被引：1，自引：0，他引：1  

Shaun Cole  Steve Hatton  David H. Weinberg  & Carlos S. Frenk 《Monthly notices of the Royal Astronomical Society》1998,300(4):945-966

  相似文献   

The radio properties of radio-quiet quasars     

Marek J. Kukula  James S. Dunlop  David H. Hughes  & Steve Rawlings 《Monthly notices of the Royal Astronomical Society》1998,297(2):366-382

Although radio-quiet quasars (RQQs) constitute ≳ 90 per cent of optically identified quasar samples, their radio properties are only poorly understood. In this paper we present the results of a multi-frequency VLA study of 27 low-redshift RQQs. We detect radio emission from 20 objects, half of which are unresolved (≤ 0.24 arcsec). In cases where significant structure can be resolved, double, triple and linear radio sources on scales of a few kpc are found. The radio emission (typically) has a steep spectrum (α ∼ 0.7, where S  ∝ ν^−α), and high brightness temperatures ( T _B ≥ 10⁵ K) are measured in some of the radio components. The RQQs form a natural extension to the radio luminosity–absolute magnitude distribution of nearby Seyfert 1s. We conclude that a significant fraction of the radio emission in RQQs originates in a compact nuclear source directly associated with the quasar. There are no significant differences between the radio properties of RQQs with elliptical hosts and those in disc galaxies within the current sample.  相似文献